Synthesis, Characterization and Electrical Conductivity of Transition Metal Complexes of Tri-Thiocarbonate and Phenol-Thiourea Based Ligand

Abstract

Mixed heterobimetallic ligand complexes of type [M(CS₃)₂][M'(L)₂], [Cu Co(CS₃)₂(L)₂] and [Cu(CS₃)₂][VO(L)₂.H₂O] have been formulated and spectroscopically characterized using IR, ¹H & ¹³C-NMR, UV-Visible, and ESR spectroscopy (where M= Cu(II) and M'= Co(II), Ni(II) & Zn(II) and L= 4-nitrophenolbenzaldehydethydethiourea based ligand (L). The powder XRD patterns of the complexes were also analyzed. It has discussed the room temperature solid state electrical conductivity and structural dimensions of these complexes.